Enantioselective metallo-organocatalyzed preparation of cyclopentanes bearing an all-carbon quaternary stereocenter.
نویسندگان
چکیده
Enantioselective metallo-organocatalyzed carbocyclizations of formyl-alkynes have been developed. The cooperation between aminocatalysis and a chiral copper(I) complex granted access to enantio-enriched cyclopentanes through the challenging formation of all-carbon quaternary stereocenters.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 52 شماره
صفحات -
تاریخ انتشار 2012